Suppose $L$ is a link with n components and the rank of $Kh(L;Z/2)$ is $2^n$, we show that $L$ can be obtained by disjoint unions and connected sums of Hopf links and unknots. This result gives a positive answer to a question asked by Batson-Seed, and generalizes the unlink detection theorem of Khovanov homology by Hedden-Ni and Batson-Seed. The proof relies on a new excision formula for the singular instanton Floer homology introduced by Kronheimer and Mrowka. This is joint work with Yi Xie.